A Facile Synthesis of N-Alkoxycarbonyl Aziridines from Olefins Bearing Two Geminal Electron-Withdrawing Groups

Stefania Fioravanti; Alberto Morreale; Lucio Pellacani; Paolo A. Tardella

doi:10.1055/s-2001-17707

PAPER

A Facile Synthesis of N-Alkoxycarbonyl Aziridines from Olefins Bearing Two Geminal Electron-Withdrawing Groups

Stefania Fioravanti*, Alberto Morreale, Lucio Pellacani*, Paolo A. Tardella*
Dipartimento di Chimica, Università ”La Sapienza", P.le Aldo Moro 2, 00185 Roma, Italy
Fax: +39(06)490631; e-Mail: pellacani@uniroma1.it;

Abstract

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Abstract

Nosyloxycarbamates react with unsaturated β-dicarbonyl compounds at room temperature in the presence of calcium oxide to give N-alkoxycarbonyl aziridines in high yield.

Key words

aminations - bicyclic compounds - carbamates - aza-Michael additions - enones

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References

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